What is the most expensive red wine? Expensive Red Wines 1 Piedmont, Italy. 2007 Gaja Barbaresco ($210) Italy’s Angelo Gaja has received so much acclaim that one might assume the hype about his wines exceeds the quality. 2 Tuscany, Italy. … 3 Napa Valley, California. … 4 Victoria, Australia. … 5 Rioja, Spain….
